Acids and bases summary

Some common acids include sulfuric acid (H2SO4), hydrochloric acid (HCl), nitric acid (HNO3) and ethanoic acid (CH3COOH).

Common bases include group 1 and 2 metal hydroxides (NaOH, KOH, LiOH, Ba(OH)2, Ca(OH)2).

Metal oxides are usually basic and non-metal oxides are usually acidic.

Concentration of a solution is usually measured in mol/dm3, where the concentration can be calculated from the number of moles divided by the volume.

Acids

An acid dissociates to give hydrogen ions (H+) in aqueous solution.

In a strong acid, the molecule completely dissociates in aqueous solution, whereas a weak acid only partially dissociates.

Neutralization occurs in the reaction between an acid and a base, where a neutral solution is created.

H+(aq) + OH-(aq) –> H2O(l)

pH scale

The pH scale measures the concentration of hydrogen ions in a solution.

A pH of 7 is neutral, below 7 is acidic and above 7 is basic.

The pH scale is a logarithmic scale where each pH step increase is a change of 10x the concentration of hydrogen ions.

pH can be calculated from pH = -log [H+]

Measuring pH

A pH meter can be used to measure pH.

Indicators are substance that change colour depending on the pH.

Some common indicators include universal indicator (which is a mix of different substances), bromothymol blue, phenolphthalein and litmus.

Reactions of acids

Acids react with bases to give a metal salt and water.

Acids react with carbonates and hydrogen carbonates to give a metal salt, carbon dioxide and water.

Acids react with metals above hydrogen in the reactivity series (including zinc, magnesium and iron) to give a metal salt and hydrogen.

Titration

Acid-base titration is a method for measuring the concentration of an acid using a base of known concentration (or vice versa).

A pipette and burette can be used to make precise measurements in a titration.

The equivalence point is where the volume of acid and base added is just right so that neither is in excess.

For a strong acid and base, the equivalence point will be at neutral pH.

To calculate the concentration from titration data, the formula C1V1 = C2V2 can be used.

 

 

Leave a comment